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Allergy friendly cafe with good nut knowledge Coffee cup science Coffee review Home experiments Observations Tea

Coffee chemistry at Estate Office Coffee

Could it really be true that the tables were reclaimed school science desks? I had read a review of Estate Office Coffee by Beanthere.at on London’s Best Coffee that had made this surprising claim (together with favourable comments about the coffee and cakes). Like a red flag to a bull, a visit was inevitable. Would there be any clues left on the tables as reminders of the past history? In the absence of many photos of the interior of the café, my mind wandered to images of long wooden benches like the physics labs in my old school. I imagined enjoying a coffee at such a bench, seated on a wooden stool, my feet not able to reach the ground. So when I arrived outside the cute little building, I was a bit puzzled as to how a whole lab could fit inside! Going in, my images of rows of coffee-table-lab-benches were metaphorically thrown out the window. Instead, a set of modern looking (small) tables were arranged so that several groups of 2-4 people could sit and enjoy their coffee together or individually. A lovely, friendly, space for conversation with friends but not quite the lab I had imagined. The counter, which was on the right as we entered, had a great array of muffins and cakes arranged on it which proved irresistible (and they knew which allergens were in which cake, so a definite tick in the ‘allergy friendly’ café box). The coffee (from Allpress espresso) was also very good and we ‘retired’ to a table to enjoy coffee and cake together.

interior Estate Office Coffee
Clearly science labs have changed since I was at school! The tables in Estate Office Coffee are reclaimed lab benches.

Although warm that day, sitting near the window was a very pleasant way of slowing down and noticing things. Moreover, the local history that is framed on the wall near the door, provided an interesting diversion for understanding how this quirky building came to be (and to survive in its present form). Copies of Caffeine magazine were also lying around adding to the large number of things that you could think about rather than revert to checking your phone. Finally though, curiosity got the better of me and I asked, were the tables really old school science lab benches? The helpful barista wasn’t absolutely sure and so texted the owner to enquire. Fairly quickly an answer came back: yes indeed, the wood had been reclaimed and used to be laboratory benches. Either school science labs have changed a bit since I attended or the tables have undergone a refurbishment as well as a reclaim, but nonetheless what a feature! Together we looked underneath the tables and noticed the parallel grooves running along the underside of the wood. What were they used for? Pens? Drainage channels for spilt chemicals? The mind boggled. But then returning to our table, we noticed that despite the lovely varnish and careful refurbishment, our table showed evidence of previous science lab use. Two circular stains as if the wood varnish had been etched by a strong acid. Immediately this took me back to experiments-gone-wrong with a home chemistry set but then it set off a whole different thought train through a slightly lateral connection to acidity and coffee.

table detail, inside Estate Office Coffee
Evidence of a past life?
Two rings in the varnish on one of the tables at Estate Office Coffee.

The issues and science associated with acidity in coffee have been discussed many times elsewhere and so if you would like to follow that train of thought you can do so here or here. Instead, I was reminded that the Arrhenius definition of acidity was that of a substance that, when in solution, increased the concentration of H+ ions in the water. For reasons that will become clear, this reminded me of stories I had heard of expert coffee-tasters who always use the same spoon when cupping coffee. Were there actually very good reasons that these coffee tasters always insist on using their own, same spoon, in every cupping session?

The connection between acidity and the spoons used for cupping comes via the ability of substances to gain or lose electrons to become ions. In the case of acids, the ion is H+ but different elements form their ionic counterparts more or less easily. This means that it is easier to take two electrons from the element copper (Cu) to form Cu2+ than it is to remove one electron from gold (Au) to form Au+. The ‘ability’ of a substance to gain (or lose) electrons is measured by the standard electrode potential. A few years ago, a group at the Institute of Making investigated whether different teaspoons made from different metals tasted different. In a blind taste test involving 32 participants, not only did they find that the spoons tasted different (as measured by bitter, metallic, strong etc), those metals that were more likely to form ionic species in solution (as indicated by the standard electrode potential) consistently tasted more bitter and more metallic than the rest: copper and zinc teaspoons tasted metallic, chrome and stainless steel tasted the least.

coffee at EOC Streatham
The important thing is how this tastes. What is the influence of cup size, shape, colour on your perception of the taste of coffee?

What was more interesting though was that the investigators then turned to the question: does the type of spoon used influence the taste of a substance? Although they investigated ice cream rather than coffee, the tastes they were looking at (bitter, sweet, salty, sour) are very relevant to coffee tasting. Again, the authors did a study involving a series of blind taste tests, this time involving 30 participants. Again, the teaspoons used were identical to each other apart from the fact that each had been electroplated with a different metal (gold, copper, zinc or stainless steel). Again there appeared to be a dependence between the taste of the substance (ice cream) and the standard electrode potential of the metal used for the spoon. When the ice cream (which had been separately flavoured to be more salty, bitter, sweet, sour or left plain) was blind-tasted with zinc or copper spoons, the ice cream was consistently rated more bitter than when tasted with stainless steel spoons. But there was more, it seemed that the sweetness of sweet ice cream was enhanced by the copper and zinc spoons. Indeed, copper and zinc spoons seemed generally to enhance the dominant taste of the ice cream (sweet became more sweet, salty more salty etc). Although spoons made of these two metals were also rated as tasting metallic, the most pleasant blind-tested ice cream-spoon combination was the sweet ice cream tasted with the copper or zinc spoons.

So it would appear that the material that the spoon is made from could influence our perception of the taste of the food or drink we consume with it. The taste of coffee could be influenced by the type of metal spoon that is used to taste it with. Other studies have emphasised the psychological importance to taste of the appearance or weight of the spoon. For consistent cupping therefore, it may very well be a good idea to stick to your favourite spoon.

However, this seems an area in which anyone can do a bit of kitchen-top coffee science experimentation. Have you blind taste tested several coffees? What about different coffees with different spoons? For those who cup coffee regularly it would be fascinating to hear your thoughts on the influence of the spoon on the taste of coffee. For those of you new to coffee cupping, you can find a how-to at the bottom of this post and then please do share your experiences. In the meanwhile, you may be pleased to return in our imaginative journey to Estate Office Coffee where a great tasting coffee can be enjoyed in a non-metallic cup and where you may additionally pause to ponder the influence of your surrounding environment on the pleasure you derive from your coffee.

Estate Office Coffee can be found at 1 Drewstead Road, Streatham, SW16 1LY

 

 

 

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cafe with good nut knowledge Coffee review Home experiments Observations Tea

Electrifying coffee at the Black Penny

Black Penny coffee London
The Black Penny on Great Queen St

Back in the seventeenth and eighteenth centuries, coffee houses were places to go for debate, discussion or even to learn something new. The Grecian was known for science. Maths instruction (particularly for gambling) could be found with Abraham de Moivre (1667-1754) at Old Slaughter’s on St Martin’s Lane. Other coffee houses were meeting centres for literature, politics, philosophy or even espionage*. Coffee houses became known as “Penny Universities”. The Black Penny on Great Queen St is a café that wants to continue this tradition, with a downstairs “seminar pit” ready to host such discussions. Although the events page still says “coming soon”, if the events do indeed come, this is very much something that’s worth keeping an eye on.

Even without the seminars though, The Black Penny is definitely worth a visit. Entering from the street, the bar is on the left and is stocked with a good looking selection of cakes. We were shown through to the relatively large, bright and airy seating area at the back where a jar of water (infused with cucumber and mint) had been put on the table for us. I had a very good long black and a lovely apple and blackberry muffin with which to take in my surroundings. The muffin was confidently asserted to be nut-free, and so the Black Penny gets a tick in the ‘good nut knowledge’ section on the Daily Grind. The coffee beans were roasted by the Black Penny themselves and while it still says that they serve ‘Alchemy’ coffee on their website, this no longer appears to be the case.

Duracell batteries as coat hooks, battery, batteries
A strange form of coat hook? The things that catch your eye in cafes

Inside, there are some very interesting architectural features to notice, the remains of a ceiling for example (now removed to reveal the roof) and the acoustics introduced by the speaker positioning. Downstairs in the seminar pit there is apparently a very old stove, though I didn’t get to see that on my visit. However, what immediately struck my eye was what appeared to be a series of coat hooks that looked very similar to a well known brand of battery. Quite what these hooks were for or why they looked like batteries I didn’t manage to ascertain, however, it did get me thinking, can you use coffee-power to light an LED?

You may have heard of a potato battery, or a lemon battery. These are often used in science outreach experiments in schools to demonstrate electricity, or the concepts of current/voltage. Made from an ordinary potato (or a lemon), a copper wire is stuck into one end of the potato and a different metal (usually zinc) is stuck into the other end of the potato. At the Black Penny, there were three things left on the table. My coffee, the mint and cucumber infused water and the tea of my accomplice in many of these reviews (I’d eaten the muffin). Which of these would perform better as a battery?

coffee power
Can 6 coffee ‘cells’ with aluminium and copper electrodes light up an LED? (The answer may be in the photo)

Although people suggest using galvanised screws as the source of the zinc electrodes, I didn’t have many of those to hand and so had to manage with aluminium foil for one electrode, copper wire for the other. By putting the aluminium on one side of a shot glass, the copper wire on the other and then filling the glass with coffee, I was able to get 0.5-0.8V across the electrodes when I measured it with my digital multimeter (DMM). Fantastic you may think, almost an AA battery, but then if you were to measure the voltage across the water rather than coffee, you will find that you get a voltage of 0.6-0.7V. The result for tea was, perhaps unsurprisingly, about 0.6V.

But voltage is not the whole story. A battery does not just supply a voltage, it gives a current. The current depends on the electrical conductance of the liquid that the electrodes are in. In the case of the potato or the lemon battery, the acid (phosphoric or citric respectively) means that there are free hydrogen ions in the ‘battery’ between the electrodes which mean the electric current can flow through the circuit. Coffee consists of many acids (chlorogenic, quinic, citric etc etc.) and so it seems sensible to ask if coffee could be used to produce a battery with a current that could power an LED? LEDs require both voltage and current, (1.6V and 10mA for the LEDs used here). Hooking up a series of coffee battery-cells meant that, by 6 ‘cells’, I had 3V across the contacts. However the electric current through the coffee battery was very low (the maximum current I recorded using the low acidity Roasting House Sierra de Agalta Honduran coffee prepared in a cafetière was 155 μA). Although this was higher than the current through water (max 81 μA), it is much lower than the current through white vinegar (770 μA under the same conditions). Consequently, in order to light the LED connected to my coffee battery, I had to add salt to each coffee cell which serves as a way of massively boosting the current through the coffee (salt forms a solution of Na+ and Cl- ions that conduct electricity through the coffee). Though even then, my LED only lit dimly and intermittently.

battery, Volta, Como museum, Como
How it should be done. The “Alessandro Volta Temple” in Como, Italy, is a fantastic place to learn about the history of electricity

Sadly then, I do not see coffee power as a future for lighting in our cafés, (unless you want to use bulletproof coffee with salted butter). However, it has started to make me wonder, could we use a single coffee-cell to monitor the acidity of our coffee? If you find a method of brewing or a particular coffee especially acidic, it should produce a higher current for the same voltage through the cell, or equivalently, the resistance of the coffee-cell should decrease as the acidity of your coffee increases. Although obviously, it would be a bad idea to drink the coffee after putting it into a cell with copper and zinc (or aluminium) electrodes, you could pour a small amount of your coffee into a shot glass to test it while you were drinking the rest of the coffee. I intend on testing this hypothesis over the next couple of weeks but in the meanwhile, if you have thoughts on this to share (or the results of your experiments), please let me know either via the comments section, email, Facebook or Twitter.

The Black Penny is at 34 Great Queen St, WC2B 5AA

* A history of coffee houses can be found in “London Coffee Houses”, Bryant Lillywhite, (1963)