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Coffee cup science Observations

A shocking coffee connection

There have been some fantastic thunderstorms in London lately. Perhaps nothing to rival thunderstorms in the tropics but for this region of the world they were quite impressive. One lightning storm in particular came very close. Thank goodness for lightning conductors! Perhaps the connection between lightning storms and coffee is not obvious. But maybe this is because you mop up your coffee spillages too quickly.

Reynolds, rain, waves, pond, raining
There are so many coffee-physics connections with rain and weather. It’s worth looking out for more.

The link is in the mess and the maths. It turns out that the maths describing water evaporating out of a drying coffee droplet is the same, in one crucial detail, as the maths describing the electric fields around a lightning conductor. If we want to see why this may be, we need to get a little bit messy and spill some coffee.

The question is how do coffee rings form? We know that to start with the solids in the coffee are distributed fairly evenly throughout the drink. It is the same when you spill it, initially a spilled drop of coffee looks like, well, coffee. But if you wait as this spilled coffee dries, you will find that a ring starts to form around the edge of the drop. How? How does a uniform coffee distribution when the drop is first spilled become a ring of coffee solids around the edge of the dried drop?

coffee ring, ink jet printing, organic electronics
Why does it form a ring?

A number of different aspects of physics feed into this problem but the one that is relevant to the lightning conductors concerns how the water in the drop evaporates. If you think about how a water molecule escapes (evaporates from) the droplet, it is not going to go shooting off like a rocket blasted out from the drop. Instead it will take a step out the drop then encounter a molecule in the air and get deflected to a slightly different path and again, and again, and so on. It follows the same sort of “random walk” that we know that the bits of dust on a coffee surface follow (and the same sort of random walk that provides a link between coffee and the movements of the financial stock exchange but that is a whole other topic).

Now think about the shape of that spilled coffee drop. If a water molecule were to evaporate from the top of the dome of the drop, it has a certain probability of escaping but it also, because its path is random, has a certain probability of re-entering the droplet. A water molecule at the edge of the droplet however will have a lower probability of re-entering the droplet purely on the basis that there isn’t so much of the droplet around it. Over many molecules and many ‘escape attempts’, this lower probability of re-absorption will translate to a higher flux of water molecules evaporating from the droplet at the edges. The water will evaporate ‘more quickly’ from the edge of the droplet than from the top of it.

artemisdraws, evaporating droplet
As the water molecules leave the droplet, they are more likely to escape if they are at the edge than if they are at the top. Image © @artemisworks

When this is written mathematically, the rate of evaporating water is related to the contact angle between the drop and the surface. The shallower the angle, the higher the rate of evaporation or equivalently, the greater the ‘flux’. It is this mathematical expression that is the same as for the lightning conductor if, rather than refer to an evaporating water flux we refer to an electric field. So the more pointy the conductor, the greater the field concentration around it. A shocking example of the idea that everything is connected.

Of course, there is much more to the coffee ring than this with physics that relates coffee rings to bacterial colonies, burning cigarette papers and soap boats. If you are interested, you can read more about how coffee rings form (including why a higher evaporation rate helps lead to a coffee ring effect) here. If on the other hand you want some well justified thinking time, go spill some coffee and watch as the coffee dries.

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General Home experiments Observations Science history slow Tea

Reflections on physics and coffee

BeanThinking started as a way of slowing down and appreciating connections, often between a coffee and the physics of the wider world but also in terms of what can be noticed in any café. Perhaps, for this first post of 2017, it’s worth spending five minutes looking at your coffee while you drink it to see what you notice. Here are a few coffee connections that occurred to me recently:

reflections, surface tension
Reflections on a coffee.

Parallel lines and surface reflection: The parallel lines on the ceiling of a café were reflected in a long black. Surface tension effects on the coffee meant that the reflections were curved and not at all parallel. A piece of dust on the surface of the coffee was revealed in the reflection by the curved reflections of the ceiling. Astronomers can use similar effects (where images of a star appear in a different location to that expected) to infer the presence of dark objects between distant stars and their telescope. This gravitational lensing can be used to detect quasars or clusters of galaxies.

 

 

 

layering of coffee long black
Layers of coffee

Layering of crema as the coffee is consumed: The coffee stain effect and this layering of the crema suggests a connection between a coffee cup and geology. It used to be my habit to take a mug of tea with me when I taught small groups of undergraduates. In the course of one of these tutorials, a student (who had been observing similar layering in my tea mug) said, “You drink your tea faster when it is cooler than when it is hot”. Full marks for observation, but not sure what it said about his attention during my tutorials! Similar observations though can help geologists estimate the age of different fossils.

 

interference patterns on coffee
Bubbles in coffee

Bubble reflections: An old one but the interference patterns caused by bubbles on the surface of the coffee are full of fascinating physics. The fact that the bubbles are at the side of the cup and seem to be grouped into clusters of bubbles may also be connected with surface tension effects (although there is a piece of weather lore that connects the position of the bubbles to the weather. If anyone ever does any experiments to investigate this particular lore, I’d love to hear about them).

 

 

Coffee, Van Gogh
Art in a coffee cup

Van Gogh’s Starry Night: The effects of vortices and turbulence caused the crema of a black coffee to swirl into patterns reminiscent of this famous painting by Van Gogh. As a result of posting this image on Twitter, @imthursty sent me a link to this preprint of a paper submitted to the arxiv: the connections between Van Gogh’s work and turbulence. A great piece of coffee combining with art and science.

 

So many connections can be made between tea, coffee and science and the wider world, I’d love to see the connections that other people make. So, if you see some interesting physics, science or connections in your coffee cup, why not email me, or contact me via FB or Twitter.