experiments you can do with coffee

From fried eggs to coffee boules via milk rings

Egg no pales, coffee, garden centre — We can often see the Leidenfrost effect when we cook a fried egg. But could we see it while simultaneously preparing a coffee cocktail?

We have probably all come across the Leidenfrost effect, the splash of water into a hot frying pan causing drops of water to skirt across the hot surface before evaporating. We may even be familiar with it in frying pans and cooking surfaces. But what would happen if you swapped the frying pan surface for a (very hot) liquid surface. What happens to the Leidenfrost effect then?

One of the first differences between a frying pan and a bath of hot liquid (we’re not quite yet to the coffee bit) is that the frying pan based Leidenfrost effect requires a lot of heat: the frying pan has to be many degrees hotter than the boiling point of the liquid being levitated. But for the Leidenfrost effect to happen on liquid surfaces requires nowhere near so much heat. In some cases levitation can even occur if the liquid bath is just one degree higher than the boiling point of the levitating liquid. What makes a hot liquid so much different from a hot solid?

The first explanation could be that a liquid surface is absolutely flat at the molecular level. Frying pans and other surfaces have scratches and dents and all sorts of bumps that mean that bubbles can form at the interface and disrupt the levitation of the drop. Could this be it? Probably not as a complete explanation because people can study the Leidenfrost effect over semiconductor wafers which are also atomically flat and even there, many more degrees are needed between the temperature of the surface and the boiling point of the drop than are observed in liquid substrates.

A second explanation is that a liquid surface is able to deform a bit to support the weight of the drop above it, this means that the drop has more of a chance of remaining levitating above the liquid surface. And yet, it turns out that there is more than that happening in liquids as a recent study in a prominent physics journal showed.

If you look carefully at the surface of the coffee in the V60 jar, you will see it is bent underneath the drop on top of it. While the drop on the coffee here is not ‘floating’ because of the Leidenfrost effect (it is stable due to other effects described here), the fact that liquids may be able to bend under drops has been thought to make the Leidenfrost effect more stable on some liquid surfaces.

That study used a bath of silicone oil as the heated surface. The drops that levitated were either of two different liquids: ethanol (ordinary alcohol) or HFE-7100 (an engineered fluid designed to replace ozone depleting chemicals in certain industrial applications). What made the study so interesting was that tiny fluorescent particles were mixed with the silicone oil that allowed the researchers to see how the liquid underneath the drop was moving.

A toroidal vortex formed in the silicone oil under both the ethanol and HFE-7100 drops. We can see similar toroidal vortices in our V60 or by dripping milk into a glass of water; they are doughnut shaped regions of moving fluid, like smoke rings, they could be considered ‘milk rings’. But in this case, there was no drop entering into the bath of liquid as with the milk rings. The drop and the bath were not mixing at all. And, perhaps more puzzling, the direction of the rotation of the vortex was different for the two types of drop. For the alcohol drops, the liquid directly underneath the drop plummeted into the silicone oil before moving under and then back up to the surface to be pulled down at the centre again. Under the HFE-7100 it was different. There, the liquid at the centre of the doughnut surged up, dragged along the surface before going under and returning back once more to be pulled up at the centre of the torus.

Why would the two liquid drops show such different behaviour in the silicone oil substrate? It comes down to a competition of three forces. The first thing that you will notice is that if the levitating drop is slowly evaporating and will eventually disappear (as is the case with the frying pan), this means that it is absorbing heat from its local atmosphere in order to gain the energy needed for evaporation to occur (think about your hand getting cold after sanitising it with an alcohol liquid as the alcohol evaporates off). This means that the silicone oil immediately under the drop gets colder. Cold liquids are generally more dense than warm liquids and so the cold liquid sinks pulling the surrounding liquid down with it.

Linked with this effect is that the surface tension of a liquid decreases as the temperature of the liquid increases. This results in a flow of liquid from regions of low surface tension to regions of higher surface tension called a “Marangoni flow”. This is again something that we may have seen during the Covid-19 lockdown restrictions as videos were circulated showing the effect of soap on a layer of pepper scattered on the surface of water. The pepper retreats away from the soap because of these Marangoni flows which can in fact be very fast.

Milk rings can be formed by dripping milk into a glass of water. But similar fluid rings can also form in liquids hot enough to support cold Leidenfrost drops levitating above them.

These two effects draw the liquid down at the centre of the torus and push the liquid up at the edges, this is what dominates when ethanol is levitating above the silicone oil. In contrast, a third effect dominates for the levitating drops of HFE-7100. Both ethanol and HFE-7100 drops are evaporating above the hot silicone oil surface and as they do so, the gas that evaporates out of them under the drop flows out from the centre of the levitating drop to the edge. Just as with a gentle breeze on a pond, this vapour flow leads to a shear force on the liquid underneath that pulls the liquid out from the centre of the torus towards the edges, down and then, to complete the circle, back up through the middle.

Remarkably, despite their different rotation directions, both types of vortex contributed to keeping the drop levitating. You can read more about the study in the summary here or in the journal here.

Given that water boils at 100C and that alcohol boils at 78C, it is feasible that by dripping vodka or another strong alcohol based drink onto our freshly prepared coffee we may see a similar effect. It may certainly be worth a try. I’ll leave this as an experiment that you can tell me about on Twitter, Facebook or in the comments section below, but it is an experiment with a positive result either way. Perhaps you will see levitating alcohol drops above your coffee. But even if you don’t, you can at least keep trying until you have made an interesting coffee based cocktail.

Exploring the sound of coffee

coffee at Watch House — We’re used to thinking about the aroma of coffee and how it looks, tastes, even how it feels, but what about how it sounds?

How much attention do you pay to your brewing coffee? You know the aroma, how the coffee blooms, you anticipate the taste and feel the warmth of the steam rising off the brew. But what about the sound? Admittedly this depends on your brew method, but what about the sounds as you filled the kettle or prepared a pour over brew? It turns out that the sound of dripping water was the subject of a recent paper in Scientific Reports.

Perhaps take time to watch a tap dripping into a bowl of water. Or maybe use this as an excuse to make another coffee by drip brewing. Each drop falling onto the water (or coffee) below first deforms the water’s surface then, as far as we can see, rebounds up with a splash of a returning drop or droplets. The phenomenon of what causes the characteristic sound of the drip has been investigated for over 100 years but in 1959 it was established using high speed photography that there were four key phases to any drip sound. First, the drop fell on the liquid, then a cavity formed just under the water surface and an air bubble formed just under that. Finally the water surface recoiled leading to a jet of droplets returning from the surface. It has been thought that the sound, that ‘plink’ of the dripping tap, was caused by that trapped air bubble expanding and contracting as it moved through the water under the water’s surface¹. But this has now been confirmed, along with some other interesting, coffee related, observations using ultrafast video recording (30 000 fps for most of the work, 75 000 fps for some of the extra details).

lilies on water, rain on a pond, droplets — Like the sound of falling rain? What causes the dripping sound of a tap?

The authors of this recent paper describe what must have been a fun experiment to do, dripping water into a tank below. You can see some of the videos of the droplet entering the water by scrolling down to the “supplementary information” in the paper. Two microphones (one above, one below the water surface) recorded the sound waves coming from the dripping ‘tap’ simultaneously with the video recording so as to match the timing of the sound with what was happening in the video. The microphone above the water surface largely recorded the same sound waveform as the microphone under the water with one crucial exception. When the authors lined the tank with MDF wood, the underwater sound was ‘damped’ quite quickly, in comparison the bare tank amplified the sound and so the sound wave took much longer to decay. Above the surface however, it didn’t matter whether the tank was lined or not, the sound signal remained the same. This may sound somewhat insignificant, but it means that it cannot be the sound created by the wobbly bubble itself merely propagating through the surface of the water. If this were the case, the microphone above the water surface should show the same signal as the microphone under the water’s surface. Instead the authors suggest that the oscillating bubble causes the surface of the water immediately above it to vibrate (in the bit that is depressed owing to the droplet having fallen into it) and it is this that we hear above the water surface.

science in a V60 — Droplets on the surface of a brewing V60 may also form owing to a temperature difference between the dripping drops of coffee and the coffee ‘bath’ underneath.

It is a beautiful set of experiments but how can it link to coffee (apart from with the dripping)? It is in the way that it gives us the chance to experience our coffee with experiments involving more of our senses than just smell, touch and taste. Firstly, the study emphasises the connection between the drop’s diameter and speed to the sound of the drip (the best sounds are for drops between 1mm and 5mm diameter). This suggests that by changing the brewing parameters (whether you prepare your V60 in a jug or a mug or change the filter paper to a metal kone for example), you may hear a change in the sound of the drips. Do you? Secondly, it has been suggested that the sound that is formed is dependent on the temperature difference between the dripping drop and the water bath underneath. A temperature difference between drop and bath would also explain an odd phenomenon I noticed in the V60 a while back. Do you notice a difference in the sound of the brewing coffee when you prepare cold brew pour over as opposed to a standard breakfast brew? Lastly, the authors of this study found that they could suppress the sound of the plink by reducing the surface tension of the water bath that they were dripping water into. In their case they added washing up detergent to the bath. This seems an awful waste of coffee but is it possible that something intrinsic to our coffee brew could do the same thing? Oil will also change the effective surface tension of the water and different coffees (and different roast strengths) change the oil content of the brewed coffee. Have you noticed any change in the sound of the drips of the coffee depending on how dark a roast coffee you use?

It may not make ground-breaking science but it does offer us an opportunity to pay even more attention to our coffee. Does the sound of your coffee reveal the beauty of the physics at work just under its surface?

¹ Some history of the investigation into the dripping sound as well as the experiments can be found in: Phillips et al., “The sound produced by a dripping tap is driven by resonant oscillation of an entrapped air bubble”, Scientific Reports, 8, 9515 (2018)