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Scratching the surface in coffee week

reflections, surface tension
The effects of surface tension can be seen in the light reflected from a coffee

UK Coffee week is once again upon us meaning that all week we can be justified in thinking about, drinking, appreciating and celebrating coffee. And of course, as soon as we start to do this, we realise we have to drink, appreciate and celebrate water which is, ultimately, what really makes most of the cup of coffee. So UK Coffee Week raises money for Project Waterfall which is a charity that brings clean water to coffee growing communities. Giving something back by enjoying something good.

In keeping with the water theme, this week The Daily Grind is all about water, including an experiment that enables you to make a hole in it. As this is also the week between Palm Sunday and Easter, perhaps we could call the post “Holey water for Holy Week”.

But moving quickly to the experiment. While drinking your coffee, you may have noticed how around the edge of the cup, the coffee appears lighter, not quite so dark, as in the interior. The coffee is being bent upwards at the edge of the cup by the surface tension of the water in the coffee. Now, what happens if you add alcohol to the coffee? If you do this in your coffee cup you may well end up with an Irish coffee which may provide even more of an excuse to celebrate your coffee drinking, but if you were to put your coffee on a plate first (I know, why? but bear with me) you will get a quite different result. You will be able to make a hole in the middle of your coffee. The reason is that the surface tension of alcohol is much weaker than that of water. Consequently, if you try to mix a very thin layer of coffee with a small amount of alcohol, something slightly unexpected happens as this video shows:

The addition of a small amount of alcohol into the middle of a thin layer of water (or coffee) causes the water to recede. As the alcohol evaporates off, you are left with a dry ‘hole’ in the coffee. Why is this? It is effectively a liquid-tug-of-war on your plate. The higher surface tension in the coffee (or water) pulls against the weaker surface tension of the alcohol which eventually means that the water breaks away, leaving the hole. As the water molecules are continually moving, eventually they start to meet again over the dry spot and close the hole.

You can’t see this in your mug of course because the mixing occurs throughout the liquid while the plate ensures that this is only a surface effect.

You will need a strong alcohol, perhaps gin or vodka but please do try this experiment, let me know how you get on and enjoy the coffee, water (and alcohol) in UK Coffee week. And if you want to donate to Project Waterfall, you could either find a participating café here or donate online here.