science in a V60 – Bean Thinking

bloom on a v60 — V60 bubbles. There is much to be gained by slowing down while brewing your coffee.

Preparing a coffee with a pour-over brewer such as a V60 is a fantastic way to slow down and appreciate the moment. Watching anti-bubbles dance across the surface as the coffee drips through, inhaling the aroma, hearing the water hit the grind and bloom; a perfect brewing method for appreciating both the coffee and the connectedness of our world. The other week, while brewing a delightful Mexican coffee from Roasting House¹, I noticed something somewhat odd in the V60. Having placed it on the kitchen scales and, following brewing advice, measured the amount of coffee, I poured the first water for the bloom and then slowly started dripping the coffee through. Nothing unusual so far and plenty of opportunity to inhale the moment. But then, as I poured the water through the grind, I noticed the scales losing mass. As 100g of water had gone through, so the scales decreased to 99g then 98g and so on. It appeared the scales were recording the water’s evaporation.

science in a V60 — Bubbles of liquid dancing on the surface of a brewing coffee.

It is of course expected that, as the water evaporates, so the mass of the liquid water left behind is reduced. This was something that interested Edmond Halley (1656-1742). Halley, who regularly drank coffee at various coffee houses in London including the Grecian (now the Devereux pub), noted that it was probable that considerable weights of water evaporated from warm seas during summer. He started to investigate whether this evaporating vapour could cause not only the rains, but also feed the streams, rivers and springs. As he told a meeting of the Royal Society, these were:

“Ingredients of a real and Philosophical Meteorology; and as such, to deserve the consideration of this Honourable Society, I thought it might not be unacceptable, to attempt, by Experiment, to determine the quantity of the Evaporations of Water, as far as they arise from Heat; which, upon Tryal, succeeded as follows…”²

Was it possible that somehow Halley’s demonstration of some three hundred years ago was being replicated on my kitchen scales? Halley had measured a pan of water heated to the “heat of summer” (which is itself thought provoking because it shows just how recent our development of thermometers has been). The pan was placed on one side of a balance while weights were removed on the other side to compensate the mass lost by the evaporating water. Over the course of 2 hours, the society observed 233 grains of water evaporate, which works out to be 15g (15 ml) of water over 2 hours. How did the V60 compare?

Rather than waste coffee, I repeated this with freshly boiled water poured straight into the V60 that was placed on the scales. In keeping with it being 2017 rather than 1690, the scales I used were, not a balance, but an electronic set of kitchen scales from Salter. The first experiment combined Halley’s demonstration with my observation while brewing the Mexican coffee a couple of weeks back. The V60 was placed directly on the scales and 402g of water just off the boil was poured into it. You can see what happened in the graph below. Within 15 seconds, 2 g had evaporated. It took just a minute for the 15g of water that Halley lost over 2 hours (with water at approximately 30 C) to be lost in the V60. After six minutes the rate that the mass was being lost slowed considerably. The total amount lost over 12 minutes had been 70g (70ml).

evaporation V60 in contact with scales — A V60 filled with 400g of water just off the boil seemed to evaporate quite quickly when placed directly on the scales.

Of course, you may be asking, could it be that the scales were dodgy? 70g does seem quite a large amount and perhaps the weight indicated by the scales drifted over the course of 12 minutes. So the experiment could be repeated with room temperature water. Indeed there did appear to be a drift on the scales, but it seemed that the room temperature water got moderately heavier rather than significantly lighter. A problem with the scales perhaps but not one that explains the quantity of water that seems to have evaporated from the V60.

control — Hot water (red triangles) loses more mass than room temperature water (grey squares).

Could the 70g be real? Well, it was worth doing a couple more experiments before forming any definite conclusions. Could it be that the heat from the V60 was affecting the mass measured by the electronic scales? After all, the V60 had been placed directly on the measuring surface, perhaps the electronics were warming up and giving erroneous readings. The graph below shows the experiment repeated several times. In addition to the two previous experiments (V60 with hot water and V60 with room temperature water placed directly on the scales), the experiment was repeated three more times. Firstly the V60 was placed on a heat proof mat and then onto the scales and filled with 400g of water. Then the same thing but rather than on 1 heat proof mat, three were placed between the kitchen scales and the V60. This latter experiment was then repeated exactly to check reproducibility (experiment 4).

You can see that the apparent loss of water when the V60 was separated from direct contact with the scales was much reduced. But that three heat proof mats were needed to ensure that the scales did not warm up during the 12 minutes of measurement. Over 12 minutes, on three heat proof mats, 14g of water was lost in the first experiment and 17g in the repeat. This would seem a more reasonable value for the expected loss of water through evaporation out of the V60 (though to get an accurate value, we would need to account for, and quantify the reproducibility of, the drift on the scales).

V60 Halley — The full set: How much water was really lost through evaporation?

Halley went on to estimate the flow of water into the Mediterranean Sea (which he did by estimating the flow of the Thames and making a few ‘back of the envelope’ assumptions) and so calculate whether the amount of water that he observed evaporating from his pan of water at “heat of summer” was balanced by the water entering the sea from the rivers. He went on to make valuable contributions to our knowledge of the water cycle. Could you do the same thing while waiting for your coffee to brew?

Let me know your results, guesses and thoughts in the comments section below (or on Twitter or Facebook).

¹As this was written during Plastic Free July 2017, I’d just like to take the opportunity to point out that Roasting House use no plastic in their coffee packaging and are offering a 10% discount on coffees ordered during July as part of a Plastic Free July promotion, more details are here.

²E Halley, “An estimate of the quantity of vapour….” Phil. Trans. 16, p366 (1686-1692) (link opens as pdf)

kettle, V60, spout, pourover, v60 preparation — The new V60 “power kettle”

It was my birthday a short while ago and someone who knows me well got me a perfect present: a kettle specially adapted for making pour-over V60 style coffees. Until this point I had been struggling with a normal kettle with it’s large spout but now, I can dream that I pour like a barista. Of course, it is important to try out your birthday present as soon as you receive it. And then try it again, and again, just to make sure that it does really make a difference to your coffee. So it is fair to say, that recently I have been enjoying some very good coffees prepared with a variety of lovely beans from Roasting House and my new V60/V60 kettle combination.

Spending the time to prepare a good coffee seems to make it even more enjoyable (though it turns out that whether you agree with this partly depends on why you are drinking coffee). Grinding the beans, rinsing the filter, warming the pot, the whole process taken slowly adds to the experience. But then, while watching the coffee drip through the filter one day, I saw a coffee drop dance over the surface of the coffee. Then another one, and another, a whole load of dancing droplets (video below). Perhaps some readers of Bean Thinking may remember a few months back a similar story of bouncing droplets on soapy water. In that case, fairly large drops of water (up to about 1cm wide) were made to ‘float’ on the surface of a dish of water that had been placed on a loudspeaker.

Sadly, for that initial experiment the coffee had been made undrinkable by adding soap to it. The soap had the effect of increasing the surface viscosity of the droplets which meant that the drop could bounce back from the vibrating water surface before it recombined with the liquid. Adding soap to the coffee meant that these liquid drops could ‘float’ (they actually bounce) on the water for many minutes or even longer (for more of the physics behind this click here).

On the face of it, there are some similarities between the drops dancing on the coffee in my V60 and these bouncing droplets. As each drop falls from the filter, it creates a vibration on the surface of the coffee. The vibration wave is then reflected back at the edges of the V60 and when the next drop falls from the filter it is ‘bounced’ back up by the vibration of the coffee.

But there are also significant differences. Firstly, as mentioned, there was no soap added to this coffee (I was brewing it to drink it!). This means that the viscosity of the drops should be similar to that of ordinary water. Although water drops can be made to bounce, the reduced viscosity means that this is less likely. Secondly, the water is hot. This acts to reduce the viscosity still further (think of honey on hot toast). Perhaps other effects (such as an evaporation flux or similar) could be having an effect, but it is noticeable that although the drops “live” long enough to be caught on camera, they are not very stable. Could it be that the vibrations caused by the droplets hitting the coffee are indeed enough to bounce the incoming droplets back up but that, unlike the soapy-water, these “anti-bubbles” do not survive for very long? Or is something deeper at play? I admit that I do not know. So, over to you out there. If you are taking time to make coffee in a V60, why not keep an eye out for these bouncing droplets and then do some experiments with them. Do you think that the bounce vibration is enough to sustain the bouncing droplet – does the speed of pour make a difference? Is it associated with the heat of the coffee? I’d be interested to hear what you think.

(The original soapy-coffee bouncing droplet video).

If you see anything interesting or odd in your coffee, why not let me know, either here in the comments section below, e-mail, or over on Twitter or on Facebook.