spectroscopy – Bean Thinking

coffee Coromandel Coast, Indian Shade grown coffee — The coffee from Coromandel Coast. Chocolate, ginger and nougat. I got the chocolate and the nougat, though the taste profile changed quite significantly between brewing by a V60 or an Aeropress

The coffee from Coromandel Coast arrived in a box, in bags that were suitable for industrial composting, each printed with an elephant on the packaging. The elephant is the logo of Coromandel Coast and is a nod to the fact that all of their coffees (which include single origins and blends) originate in India. All of the coffees have been shade grown which helps with the carbon footprint of the coffee, hence the slogan “Climate solution in your cup”. Which means that it would have been easy to do a coffee-physics review based on the different ways that coffee can be grown and why shade grown coffee can be part of a climate solution for coffee. But that would have been too quick; one of the motivations for cafe-physics reviews (and the related coffee-physics reviews) is to slow down and explore how sitting down and contemplating a cafe (or just coffee) can lead to so many different but connected thought trains. Given that your attention is drawn to the issues of climate change, and what you can do, from the instant you order from Coromandel Coast, this seems to be too obvious, even if an incredibly useful, thought train. So, if you would like to follow that thought train while contemplating the coffee you are drinking, you can read more about the environmental impact of coffee growing here or here and the importance of shade grown coffee here. An alternative thought train may be provided by the elephants.

I purchased two coffees from Coromandel Coast: Ganga and Chalukya. The Ganga was a washed catuai peaberry coffee with tasting notes of “chocolate, ginger and nougat”. The chocolate definitely comes through when brewed in the V60 and the pureover while the Aeropress produces a somehow cleaner taste profile that I find characteristic of washed coffees. Coromandel Coast was established in 2017-8 and is both a coffee roaster and a cafe based in Croydon. All of the packaging is recyclable or compostable, including the box it arrives in which is additionally re-usable (and will be reused again a couple of times before it is eventually recycled).

The elephant stamp. Is every copy identical? Could we use one elephant to understand the others?

The ink-stamped elephant on the box is a nice touch and echoed on the coffee bags. You could perhaps start to think about ink printing, dyes and the invention of the printing press, there are plenty of thought-paths that open themselves out. But a chance conversation over the coffee provided a different direction into the ways in which physics is taught at schools.

It appears that the school of my interlocutor that day initiated the physics course with a very boring set of classes on units. I was asked that morning: why would the teacher have started teaching physics with such a boring set of lessons? But I wondered a separate question, how can units be boring? How sad that they were made to be so. For although they are of fundamental importance in how we explore and understand our world, and could perhaps be quite dry, they can also link elephants to the Sun and to the work we now do to understand coffee better. For if we start with elephants, it was a favourite unit of my physics teacher. Used for all manner of things when we omitted to include the units in our answers. Consider the coffee: it comes in bags of 250 what? 250 elephants? or 250 grammes? The elephant became a unit of frustration for the lack of stated proper units. But we can push the Coromandel Coast elephant link a bit further, for each elephant on the packet is an ink-stamped copy. They are different but identical, they serve as a standard.

neon sign, light emission — Light is emitted from different chemicals at certain, definite wavelengths. This is an effect you will have seen on many a high street in these neon signs where the colour is determined by the composition of the gas within the sign. We can use the reverse of this to identify chemicals based on what wavelengths they absorb. But to do that, we need to know that we are all measuring in the same units.

And the standards are important for units because we need to know that we are all measuring the same thing. When Anders Angstrom was measuring the absorption and emission spectra of the Sun and of different gases, he quoted the absorption lines in units of 1/10 of a nanometre (a unit now called the Angstrom). Different gasses will absorb (or emit) light at very specific frequencies or wavelengths. Being a very careful experimentalist, Angstrom had ensured that his measurements of the wavelengths that were absorbed or emitted were checked against the standard measure of length of the day, the metre. But at the time, the metre was defined by the length of a metal rod stored in Paris. All other standards of the metre were copies of this original one, including the metre kept at Uppsala where Angstrom was doing his experiments. An issue with metals is that they will age. With time you will get some shrinkage and some expansion owing to the formation of oxides etc. on the metal. The metre in Paris had aged in a different way to that in Uppsala which was just a tiny bit shorter than the Paris metre*. These differences would not be noticeable were Angstrom measuring the size of elephants, but instead he was concerned with measurements that were one ten-billionth of a metre. And at this scale, it mattered a great deal. Angstrom was aware of the systematic error in his results but it wasn’t until after his death that the error was fully hunted down and corrected for.

The position of the lines that Angstrom had been measuring reveal the chemical composition of the gases, and so knowing whether a line appears at 700 or 710 nm, reveals information about the chemical studied. We still use these spectroscopy techniques, not just for understanding gases, but also for checking the composition of medicines and for understanding the differences between Arabica and Robusta coffees. Which brings us back to the coffee, for while we no longer use a physical measure of length as our standard metre, we still use a standard definition of the metre that allows us to compare coffees and stellar spectra. It also allows us to appreciate the beauty in the uniformity of an ink-stamped elephant on a box housing an interesting and flavourful, climate sensitive, coffee.

You can order from Coromandel Coast here, or (post-lockdown) visit the cafe at Filtr, 53 Limpsfield Road, S. Croydon,, CR2 9LB

*To read more about the history of the definitions of units including the metre, click here. This anecdote was originally recorded in a book that I do not have physical access to at the moment owing to coronavirus restrictions. As soon as I get the name/author of the book, I’ll include it here.

Now you see it now you don’t at Bond St Coffee, Brighton

Outside Bond St Coffee Brighton — Bond St on Bond St, Brighton

A couple of weeks back, I tried the lovely Bond St. Coffee in Brighton on the recommendation of @paullovestea from Twitter. It was a Saturday with good weather and it turns out that this particular café is (understandably) very popular and so, sadly, to begin with we could only sit outside. That said, it was a lovely spring day (sunny but a bit chilly) and so it was quite pleasant to watch the world go by (or at least Bond St) while savouring a well made pour-over coffee. All around the café, the street decoration hinted at times past. Across the road what was obviously a pub in times gone by has turned into an oddities store. Air vents to a space underneath the window seating area in Bond Street café itself suggested an old storage space. A seat in the window appeared to have been re-cycled from an old bus seat.

But it was the pour-overs at Bond St. Coffee that had been particularly recommended and they certainly lived up to expectations. I had a Kenyan coffee roasted by the Horsham Roasters. The V60 arrived at our bench seat/table in a metal jug together with a drinking glass. The angle of the Sun caught the oils on the surface of the coffee, reminding me of Agnes Pockels and her pioneering experiments on surface tension. Pouring the coffee into the glass I thought about the different thermal conductivities of glass as compared to metal and how I had put both down on the wooden bench. How was heat being transferred through these three materials? And then, as I placed the metal jug back on the bench I noticed the reflections from the side of the jug and thought, just why is it that you can see through the colourless glass but the metal is grey and opaque?

Metal jug and transparent glass — Metal jug, glass cup. V60 presentation at Bond St Coffee

On one level, this question has a simple answer. Light is an electromagnetic wave and a material is opaque if something in the material absorbs or scatters the incoming light. In a metal, the electrons (that carry the electric currents associated with the metal’s high electrical conductivity) can absorb the light and re-emit it leading to highly reflective surfaces. In glass there are no “free” electrons and few absorbing centres ready to absorb the light and so it is transmitted through the glass.

Only this is not a complete answer. For a start we haven’t said what we mean by ‘glass’. The glass in the photo is indeed transparent but some glasses can be more opaque. More fundamentally though, there is a problem with the word ‘opaque’. For us humans, ‘visible’ light is limited to light having wavelengths from about 400nm (blue) to about 780nm (red). ‘Light’ though can have wavelengths well below 400 nm (deep into the UV and through the X-ray) and well above 780 nm (through infra-red and to microwaves and beyond). We can see the spread of wavelengths of light visible to us each time we see a rainbow or sun dog. Other animals see different ranges of ‘visible’ light, for example, bumble-bees can see into the ultra-violet. So, our statement that glass is transparent while metal is opaque is partly a consequence of the fact that we ‘see’ in the part of the spectrum of light for which this is true.

Sun-dog, Sun dog — Sun dogs reveal the spectrum of visible light through refraction of the light through ice crystals.

For example if, like the bumble-bee, we could see in the UV, some glass may appear quite different from the way it does to us now. Even though the glass in the photo lacks the free electrons that are in the metallic jug, there are electrons in the atoms that make up the glass that can absorb the incident light if that light has the right energy. There are also different types of bonds between the atoms in the glass that can also absorb light at particular energies. The energy of light is related to its frequency (effectively its colour*). Consequently, if the energy (frequency/ wavelength) of the light happens to be at the absorption energy of an atom or an electron in the glass, the glass will absorb the light and it will start to appear more opaque to light of that colour. Many silicate glasses absorb light in the UV and infra-red regions of the electromagnetic spectrum while remaining highly transparent in the visible region. High purity silica glass starts to absorb light in the UV at wavelengths less than approx 160nm†. Ordinary window glass starts to absorb light in the nearer UV†. In fact, window glass can start to absorb light below wavelengths of up to ~ 300 nm, the edge of what is visible to a bumble bee: The world must appear very different to the bumble bee. At the other end of the scale, chalcogenide based glasses absorb light in (our) visible range but are transparent in the infra-red.

Looking at how materials absorb light, that is, the ‘absorption spectrum’, enables us to investigate what is in a material. It is in many ways similar to a ‘fingerprint’ for the material. From drugs discovery to archaeology, environmental analysis to quality control, measuring how a material absorbs light (over a wider range of frequencies than we can see) can tell us a great deal about what is in that material.

Perhaps you could conclude that whether something is opaque or crystal clear depends partly on how you look at it.

Bond St Cafe is on Bond St, Brighton, BN1 1RD

*I could add a pedantic note here about how the colour that we see is not necessarily directly related to the frequency of the light. However, it would be fair to say that a given frequency of light has a given ‘colour’ so blue light has a certain frequency, red light a different frequency. Whether something that appears red does so because it is reflecting light at the frequency of red light is a different question.

†”Optical properties of Glass”, I Fanderlik, was published by Elsevier in 1983.